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the easiest way is to use task scheduler.
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what i do is this and then no need to system user.
mount to a folder, not drive letter like so.
rclone mount gdrive-a1b2: b:\mount\rclone\gdrive-a1b2
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if is recommend to use
--vfs-cache-mode full
when i mount for streaming, i follow @VBB recommendations about mounting as read only and priming the mount for plex scan.
Google Drive, Plex, Windows 10