Yup! I have it working well as far as I can tell.
On the Synology, login to the web gui, go to control panel, Task Scheduler.
Click on the create dropdown, triggered task.
Fill out the description name and everything. make sure you specify the shell script on the bottom including the path, and make sure you have the event as boot-up.
Of course once you have that there, do the same thing for an unmount script at shutdown.
Hope this helps!